Issue 30, 2022

Temperature-dependent behavior in the local structure of BaTiO3 nanocrystals

Abstract

We use pair distribution function analysis of synchrotron X-ray total scattering data to inspect the local structure of BaTiO3 nanocrystals from 253 K < T < 413 K. The local structure consists of ca. r = 35 Å domains in which Ti4+ displacements have the same coherence length as the overall perovskite structure.

Graphical abstract: Temperature-dependent behavior in the local structure of BaTiO3 nanocrystals

Supplementary files

Article information

Article type
Communication
Submitted
23 May 2022
Accepted
27 Jun 2022
First published
07 Jul 2022

CrystEngComm, 2022,24, 5400-5404

Author version available

Temperature-dependent behavior in the local structure of BaTiO3 nanocrystals

P. Cottingham and R. L. Brutchey, CrystEngComm, 2022, 24, 5400 DOI: 10.1039/D2CE00705C

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