Exploiting consecutive photoinduced electron transfer (ConPET) in CO2 photoreduction†
Abstract
The consecutive photoinduced electron transfer (ConPET) process of 1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) in CO2 photoreduction to achieve powerful reducing species has been disclosed by activating a bis(terpyridine)ruthenium(II) complex bearing a high overpotential for selective light-driven reduction of CO2 to CO in homogeneous solution.