New approaches to the functionalization of the 1-carba-closo-decaborate anion

Akim V. Shmal’ko; Paula Cendoya; Sergey A. Anufriev; Kyrill Yu. Suponitsky; Detlef Gabel; Igor B. Sivaev

doi:10.1039/D1CC06395B

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New approaches to the functionalization of the 1-carba-closo-decaborate anion†‡

Akim V. Shmal’ko,

^ab Paula Cendoya,^b Sergey A. Anufriev,^a Kyrill Yu. Suponitsky,

^a Detlef Gabel

^b and Igor B. Sivaev

*^a

Author affiliations

* Corresponding authors

^a A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Str, Moscow, Russia
E-mail: sivaev@ineos.ac.ru

^b Department of Life Sciences and Chemistry, Jacobs University Bremen, Campus Ring 1, Bremen, Germany

Abstract

Two new approaches to the functionalization of the 1-carba-closo-decaborate anion [1-CB₉H₁₀]⁻ at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and heteroaromatics were developed.

This article is part of the themed collection: Boron Chemistry in the 21st Century: From Synthetic Curiosities to Functional Molecules

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DOI: https://doi.org/10.1039/D1CC06395B
Article type: Communication
Submitted: 12 Nov 2021
Accepted: 18 Feb 2022
First published: 18 Feb 2022

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Chem. Commun., 2022,58, 3775-3778

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New approaches to the functionalization of the 1-carba-closo-decaborate anion

A. V. Shmal’ko, P. Cendoya, S. A. Anufriev, K. Yu. Suponitsky, D. Gabel and I. B. Sivaev, Chem. Commun., 2022, 58, 3775 DOI: 10.1039/D1CC06395B

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Chemical Communications

New approaches to the functionalization of the 1-carba-closo-decaborate anion†‡

Abstract

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New approaches to the functionalization of the 1-carba-closo-decaborate anion

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