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DOI: 10.1039/D1RA90136B (Correction) RSC Adv., 2021, 11, 27498-27498

Correction: Functionalized pyridine in pyclen-based iron(III) complexes: evaluation of fundamental properties

Magy A. Mekhail, Kristof Pota, Timothy M. Schwartz and Kayla N. Green*
Department of Chemistry and Biochemistry, Texas Christian University, 2950 W. Bowie, Fort Worth, TX 76129, USA. E-mail: kayla.green@tcu.edu

Received 3rd August 2021 , Accepted 3rd August 2021

First published on 13th August 2021

Abstract

Correction for ‘Functionalized pyridine in pyclen-based iron(III) complexes: evaluation of fundamental properties’ by Magy A. Mekhail et al., RSC Adv., 2020, 10, 31165–31170. DOI: 10.1039/d0ra05756h.

In the original article, in Table 2, incorrect values for the models for Fe(L4) were given. The correct values for the models for Fe(L4) are given in Table 2 here.
Table 2 Formation constants (log[thin space (1/6-em)]β) of the ML species formed, Fe(II)/(III)
Complex log[thin space (1/6-em)]βred log[thin space (1/6-em)]βox
Fe(II)a Fe(III)b
a I = 0.15 M NaCl and T = 25.0 °C.b Derived from eqn (1) (ref. 31) and (Fe2+)aq, E°′FeIII/FeII = −0.439 vs. [Fe(CN)6]3−/[Fe(CN)6]4−.
[Fe(image file: d1ra90136b-u1.tif)] 14.18(5) 14.57
[Fe(image file: d1ra90136b-u2.tif)] 14.46(7) 14.70
[Fe(image file: d1ra90136b-u3.tif)] 12.41(2) 12.02
[Fe(image file: d1ra90136b-u4.tif)] 13.11(2) 12.91
[Fe(image file: d1ra90136b-u5.tif)] 12.30(2) 11.44

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.

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