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We describe a self-catalyzing photoredox polymerization system for the modular generation of macromolecular photocatalysts. Specifically, we designed a photoactive eosin Y-derived monomer that can induce photoelectron/energy transfer, while simultaneously partaking in reversible addition–fragmentation chain transfer polymerization as a monomer, affording polymer catalysts with tunable eosin Y incorporations.

Graphical abstract: Self-catalyzing photoredox polymerization for recyclable polymer catalysts

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