Issue 13, 2021

Preparation of hexafluoroisopropyl esters by oxidative esterification of aldehydes using sodium persulfate

Abstract

A simple, metal-free route for the oxidative esterification of aldehydes to yield hexafluoroisopropyl esters is reported. The methodology employs sodium persulfate and a catalytic quantity of a nitroxide and is applicable to aromatic, heteroaromatic, and aliphatic aldehydes.

Graphical abstract: Preparation of hexafluoroisopropyl esters by oxidative esterification of aldehydes using sodium persulfate

Supplementary files

Article information

Article type
Paper
Submitted
08 Feb 2021
Accepted
15 Mar 2021
First published
15 Mar 2021

Org. Biomol. Chem., 2021,19, 2986-2990

Preparation of hexafluoroisopropyl esters by oxidative esterification of aldehydes using sodium persulfate

A. León Sandoval, F. Politano, M. L. Witko and N. E. Leadbeater, Org. Biomol. Chem., 2021, 19, 2986 DOI: 10.1039/D1OB00251A

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