Selective excitation doubles the transfer of parahydrogen-induced polarization to heteronuclei

Abstract

In this work, we present a new pulse sequence to transform the spin order added to a molecule after the pairwise addition of parahydrogen into ¹³C polarization. Using a selective 90° preparation instead of a non-selective 45° excitation, the new variant performed twice as well as previous implementations in both simulations and experiments, exemplified with hyperpolarized ethyl acetate. This concept is expected to extend to other nuclei and other spin order transfer schemes that use non-selective excitation.