Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

Hajime Kameo; Akihiro Mushiake; Tomohito Isasa; Hiroyuki Matsuzaka; Didier Bourissou

doi:10.1039/D1CC01392K

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Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation†‡

Hajime Kameo,

*^a Akihiro Mushiake,^a Tomohito Isasa,^a Hiroyuki Matsuzaka

^a and Didier Bourissou

*^b

Author affiliations

* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Osaka 599-8531, Japan
E-mail: h.kameo@c.s.osakafu-u.ac.jp

^b Laboratoire Hétérochimie Fondamentale et Appliquée, Université Paul Sabatier/CNRS UMR 5069, 118 Route de Narbonne, 31062 Toulouse Cedex 09, France
E-mail: dbouriss@chimie.ups-tlse.fr

Abstract

Pd/Ni → Ge–F interactions supported by phosphine-chelation were found to trigger dual activation of Ge–F bonds under mild conditions. This makes fluoro germanes suitable partners for catalytic Ge–C cross-coupling and enables Germa-Suzuki reactions to be achieved for the first time.

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DOI: https://doi.org/10.1039/D1CC01392K
Article type: Communication
Submitted: 15 Mar 2021
Accepted: 20 Apr 2021
First published: 20 Apr 2021

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Chem. Commun., 2021,57, 5004-5007

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Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

H. Kameo, A. Mushiake, T. Isasa, H. Matsuzaka and D. Bourissou, Chem. Commun., 2021, 57, 5004 DOI: 10.1039/D1CC01392K

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Chemical Communications

Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation†‡

Abstract

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Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

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