Zero-valent ML2 complexes of group 10 metals supported by terphenyl phosphanes

M. Trinidad Martín; Mario Marín; Raquel J. Rama; Eleuterio Álvarez; Celia Maya; Francisco Molina; M. Carmen Nicasio

doi:10.1039/D1CC00676B

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Zero-valent ML₂ complexes of group 10 metals supported by terphenyl phosphanes†

M. Trinidad Martín,‡^a Mario Marín,‡^a Raquel J. Rama,

^a Eleuterio Álvarez,

^b Celia Maya,^b Francisco Molina^c and M. Carmen Nicasio

*^a

Author affiliations

* Corresponding authors

^a Departamento de Química Inorgánica, Universidad de Sevilla, Aptdo 1203, Sevilla 41071, Spain
E-mail: mnicasio@us.es

^b Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC) and Universidad de Sevilla, Avenida Américo Vespucio 49, Sevilla 41092, Spain

^c Laboratorio de Catálisis Homogénea, Unidad Asociada al CSIC, CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química, Universidad de Huelva, Huelva 21071, Spain

Abstract

Bulky terphenyl phosphane ligands PMe₂Ar′ (Ar′ = terphenyl group) facilitate the isolation of zero-valent bis-phosphane complexes of nickel, palladium and platinum. The former show coordination numbers greater than two in the solid state due to the existence of Ni–C_arene interactions with the terphenyl fragment.

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Article information

DOI: https://doi.org/10.1039/D1CC00676B
Article type: Communication
Submitted: 04 Feb 2021
Accepted: 23 Feb 2021
First published: 23 Feb 2021

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Chem. Commun., 2021,57, 3083-3086

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Zero-valent ML₂ complexes of group 10 metals supported by terphenyl phosphanes

M. T. Martín, M. Marín, R. J. Rama, E. Álvarez, C. Maya, F. Molina and M. C. Nicasio, Chem. Commun., 2021, 57, 3083 DOI: 10.1039/D1CC00676B

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Chemical Communications