Issue 28, 2021
From the journal:

Chemical Communications

Entropy differences between hydrides and other elements†

Yoshitsugu Kojima ORCID logo *a  and  Masakuni Yamaguchib  

* Corresponding authors

a Natural Science Center for Basic Research and Development, Hiroshima University, 1-3-1, Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8530, Japan

b Graduate School of Advanced Sciences of Matter, Hiroshima University, 1-3-1, Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8530, Japan

Abstract

The standard entropy differences between hydrides and other elements (metals, liquid N2, toluene) ΔS were increased with the volume differences ΔV. It was found that ΔS is roughly expressed by the following equation, |ΔS| ∝ Rln|ΔV|, in which R is the gas constant.

Graphical abstract: Entropy differences between hydrides and other elements

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Article information

DOI
https://doi.org/10.1039/D0CC07107B
Article type
Communication
Submitted
27 Oct 2020
Accepted
01 Mar 2021
First published
02 Mar 2021

Chem. Commun., 2021,57, 3461-3463

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Entropy differences between hydrides and other elements

Y. Kojima and M. Yamaguchi, Chem. Commun., 2021, 57, 3461 DOI: 10.1039/D0CC07107B

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