High temperature Fe(III) spin crossover behaviours in three unprecedented FeIII–MII–FeIII (M = Fe, Cd) linear trinuclear complexes

Zhi-Jian Ouyang; Xiao-Ying Mo; Meng Yang; Li Zhong; Wen-Bin Chen; Song Gao; Wen Dong

doi:10.1039/C9QI01560D

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High temperature Fe(iii) spin crossover behaviours in three unprecedented Fe^III–M^II–Fe^III (M = Fe, Cd) linear trinuclear complexes†

Zhi-Jian Ouyang,^a Xiao-Ying Mo,^a Meng Yang,^a Li Zhong,^a Wen-Bin Chen,

^a Song Gao

^b and Wen Dong

*^a

Author affiliations

* Corresponding authors

^a Guangzhou Key Laboratory for Environmentally Functional Materials and Technology, School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, P. R. China
E-mail: 1942631634@qq.com

^b School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, P. R. China

Abstract

An azo-based ligand of azotetrazolyl-2,7-dihydroxynaphthalene (H₃ATD) was used to synthesize three unprecedented Fe^III–M^II–Fe^III (M = Fe, Cd) linear trinuclear complexes with different high temperature spin crossover (SCO) behaviours for the terminal Fe^III ions.

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Article information

DOI: https://doi.org/10.1039/C9QI01560D
Article type: Research Article
Submitted: 29 Nov 2019
Accepted: 31 Jan 2020
First published: 04 Feb 2020

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Inorg. Chem. Front., 2020,7, 1526-1531

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High temperature Fe(III) spin crossover behaviours in three unprecedented Fe^III–M^II–Fe^III (M = Fe, Cd) linear trinuclear complexes

Z. Ouyang, X. Mo, M. Yang, L. Zhong, W. Chen, S. Gao and W. Dong, Inorg. Chem. Front., 2020, 7, 1526 DOI: 10.1039/C9QI01560D

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