Issue 39, 2020

Organic synthesis of fixed CO2 using nitrogen as a nucleophilic center

Abstract

In this review, recent progress in the application of CO2 as an electrophilic reagent and nitrogen as a nucleophilic center under different catalytic conditions in organic synthesis is summarized. The used catalytic methods in the reactions of CO2 and nitrogen are classified as metal catalysis, metal-free catalysis, photocatalysis and electrocatalysis. Various catalytic conditions have been used to solve the problems of thermodynamic properties and stability of CO2. The transformation mechanisms of these reactions are discussed.

Graphical abstract: Organic synthesis of fixed CO2 using nitrogen as a nucleophilic center

Article information

Article type
Review Article
Submitted
01 Aug 2020
Accepted
25 Aug 2020
First published
25 Aug 2020

Org. Biomol. Chem., 2020,18, 7774-7788

Organic synthesis of fixed CO2 using nitrogen as a nucleophilic center

T. Xiong, X. Li, M. Zhang and Y. Liang, Org. Biomol. Chem., 2020, 18, 7774 DOI: 10.1039/D0OB01590C

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