Issue 13, 2020

Metal-free synthesis of imino-disaccharides and calix-iminosugars by photoinduced radical thiol–ene coupling (TEC)

Abstract

Radical thiol–ene coupling was exploited for the first time to prepare imino-disaccharides and multivalent iminosugars starting from sugar thiols and iminosugar alkenes or iminosugar thiols and tetra-allylated calixarene, respectively.

Graphical abstract: Metal-free synthesis of imino-disaccharides and calix-iminosugars by photoinduced radical thiol–ene coupling (TEC)

Supplementary files

Article information

Article type
Communication
Submitted
30 Jan 2020
Accepted
13 Feb 2020
First published
21 Feb 2020

Org. Biomol. Chem., 2020,18, 2392-2397

Metal-free synthesis of imino-disaccharides and calix-iminosugars by photoinduced radical thiol–ene coupling (TEC)

R. Zelli, P. Dumy and A. Marra, Org. Biomol. Chem., 2020, 18, 2392 DOI: 10.1039/D0OB00198H

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