Combining unsaturated metal sites and narrow pores within a Co(II)-based MOF towards CO2 separation and transformation

Xiuling Zhang; Ran-Hui Zhang; Hui Hu; Longlong Geng; Yong-Zheng Zhang; Jun Gao; Da-Shuai Zhang; Yao-Qiang Jin; Jianmin Sheng

doi:10.1039/C9DT04736K

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Combining unsaturated metal sites and narrow pores within a Co(ii)-based MOF towards CO₂ separation and transformation†

Xiuling Zhang,

^ab Ran-Hui Zhang,^a Hui Hu,^b Longlong Geng,

^b Yong-Zheng Zhang,^b Jun Gao,

^c Da-Shuai Zhang,

*^ab Yao-Qiang Jin^a and Jianmin Sheng^d

Author affiliations

* Corresponding authors

^a College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao, P. R. China
E-mail: dashuai_74@163.com

^b College of Chemistry and Chemical Engineering, Dezhou University, Dezhou, P. R. China

^c College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, P. R. China

^d College of Medicine and Nursing, Dezhou University, Dezhou, P. R. China

Abstract

A Co(II)-based MOF, {[Co₃(L)₂(bpb)(DMA)(H₂O)]·Solvents}_n (RH-1), with a unique interpenetrated framework has been solvothermally prepared. Because of its unsaturated metal sites and narrow pores inside the framework, RH-1 demonstrated excellent selective CO₂ adsorption over N₂ and CH₄ and good performance in catalytic CO₂ conversion to cyclic carbonates under mild conditions.

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Article information

DOI: https://doi.org/10.1039/C9DT04736K
Article type: Communication
Submitted: 13 Dec 2019
Accepted: 20 Jan 2020
First published: 20 Jan 2020

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Dalton Trans., 2020,49, 2058-2062

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Combining unsaturated metal sites and narrow pores within a Co(II)-based MOF towards CO₂ separation and transformation

X. Zhang, R. Zhang, H. Hu, L. Geng, Y. Zhang, J. Gao, D. Zhang, Y. Jin and J. Sheng, Dalton Trans., 2020, 49, 2058 DOI: 10.1039/C9DT04736K

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