Issue 22, 2020
From the journal:

Physical Chemistry Chemical Physics

Structural characterization of molybdenum–dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy†

Akira Yamamoto, ORCID logo *ab   Kazuya Arashiba,c   Shimpei Naniwa, ORCID logo a   Kazuo Kato,d   Hiromasa Tanaka,e   Kazunari Yoshizawa, ORCID logo f   Yoshiaki Nishibayashi ORCID logo *c  and  Hisao Yoshida ORCID logo *ab  

* Corresponding authors

a Department of Interdisciplinary Environment, Graduate School of Human and Environmental Studies, Kyoto University, Yoshida Nihonmatsu-cho, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: yamamoto.akira.2a@kyoto-u.ac.jp

b Elements Strategy Initiative for Catalysts & Batteries (ESICB), Kyoto University, Kyotodaigaku Katsura, Nishikyo-ku, Kyoto 615-8520, Japan

c Department of Systems Innovation, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

d Japan Synchrotron Radiation Research Institute, SPring-8, Sayo, Hyogo 679-5198, Japan

e School of Liberal Arts and Sciences, Daido University, Minami-ku, Nagoya 457-8530, Japan

f Institute for Materials Chemistry and Engineering, Kyushu University, Nishi-ku, Fukuoka 819-0395, Japan

Abstract

The structural characterization of a hardly-isolatable molybdenum–dinitrogen complex bearing a PNP-type pincer ligand, which is assumed to be a key reactive complex in the stoichiometric transformation of a molybdenum triiodide complex [MoI3(PNP)] into the corresponding molybdenum nitride complex under an atmospheric pressure of dinitrogen, was carried out by using dispersive XAFS.

Graphical abstract: Structural characterization of molybdenum–dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy

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Article information

DOI
https://doi.org/10.1039/C9CP06761B
Article type
Communication
Submitted
16 Dec 2019
Accepted
22 Apr 2020
First published
23 Apr 2020

Phys. Chem. Chem. Phys., 2020,22, 12368-12372

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Structural characterization of molybdenum–dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy

A. Yamamoto, K. Arashiba, S. Naniwa, K. Kato, H. Tanaka, K. Yoshizawa, Y. Nishibayashi and H. Yoshida, Phys. Chem. Chem. Phys., 2020, 22, 12368 DOI: 10.1039/C9CP06761B

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