Constructing and controlling ruthenium active phases for acetylene hydrochlorination

Bolin Wang; Yuxue Yue; Saisai Wang; Zhi Chen; Lu Yu; Shujuan Shao; Guojun Lan; Zhiyan Pan; Jia Zhao; Xiaonian Li

doi:10.1039/D0CC04382F

Constructing and controlling ruthenium active phases for acetylene hydrochlorination†

Bolin Wang,‡^ab Yuxue Yue,‡^a Saisai Wang,^a Zhi Chen,^a Lu Yu,^a Shujuan Shao,^a Guojun Lan,^a Zhiyan Pan,

^b Jia Zhao

*^a and Xiaonian Li*^a

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* Corresponding authors

^a Industrial Catalysis Institute of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Hangzhou, P. R. China
E-mail: jiazhao@zjut.edu.cn, xnli@zjut.edu.cn

^b College of Environment, Zhejiang University of Technology, Hangzhou 310014, P. R. China

Abstract

Ru-Based catalysts with distinct active phases from Ru⁰, to RuO₂, RuCl₃ and RuCl₂N were synthesized and evaluated in acetylene hydrochlorination. RuCl₂N is identified as the efficient active phase due to its co-activation of acetylene and hydrogen chloride. This discovery holds great potential to accelerate the large-scale application of Ru-based catalysts in industry.

Chemical Communications

Constructing and controlling ruthenium active phases for acetylene hydrochlorination†

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Constructing and controlling ruthenium active phases for acetylene hydrochlorination

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