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Methacrylated lignin was reacted with PH3(g) to prepare a phosphorus rich bio-based polymer containing PH/PH2 functional groups, which were converted to tertiary phosphine units via the phosphane-ene reaction. This represents a straightforward method for the upconversion of low-value biomass waste to useful inorganic polymer with potential utility in metal scavenging applications.

Graphical abstract: “Lignophines”: lignin-based tertiary phosphines with metal-scavenging ability

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