Zhaoqiang Zhang, Qi Ding, Shing Bo Peh, Dan Zhao, Jiyu Cui, Xili Cui and Huabin Xing
Chem. Commun., 2020,56, 7726-7729
DOI:
10.1039/D0CC03196H,
Communication
An ultramicroporous MOF, ZU-36-Ni (GeFSIX-3-Ni) is obtained for the first time via a mechanochemical-assisted approach. The material exhibits excellent performance for trace CO2 capture (1.07 mmol g−1 at 400 ppm) and benchmark 50/50 CO2/CH4 selectivity of 930, which is proven by dynamic breakthrough tests.