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An ultramicroporous MOF, ZU-36-Ni (GeFSIX-3-Ni) is obtained for the first time via a mechanochemical-assisted approach. The material exhibits excellent performance for trace CO2 capture (1.07 mmol g−1 at 400 ppm) and benchmark 50/50 CO2/CH4 selectivity of 930, which is proven by dynamic breakthrough tests.

Graphical abstract: Mechano-assisted synthesis of an ultramicroporous metal–organic framework for trace CO2 capture

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