Issue 23, 2020

A micro passive preconcentrator for micro gas chromatography

Abstract

We describe a microfabricated passive preconcentrator (μPP) intended for integration into gas chromatographic microsystems (μGC) for analyzing volatile/semi-volatile organic compounds (S/VOC). Devices (8 × 8 mm) were made from a silicon-on-insulator top layer and a glass bottom layer. The top layer has 237 apertures (47 × 47 μm) distributed around the periphery of a circular region (5.2 mm o.d.) through which ambient vapors diffuse at predictable rates. Two internal annular cavities offset from the apertures are packed with ∼800 μg each of commercial carbon adsorbents. Thin-film heaters thermally desorb captured vapors, which are drawn by a pump through a central exit port to a micro injector for analysis with a bench scale GC. The 15 test compounds spanned a vapor pressure range of 0.033 to 1.1 kPa. Effective (diffusional) μPP sampling rates ranged from 0.16 to 0.78 mL min−1 for short-duration exposures to ∼mg m−3 vapor concentrations. Observed and modeled sampling rates generally agreed within 15%. Sampling rates for two representative compounds declined by ≤30% between 0.25 and 24 h of continuous exposure. For one of these, the sampling rate declined by only 8% over a ∼2300-fold concentration range (0.25 h samples). Desorption (transfer) efficiencies were >95% for most compounds (250–275 °C, 60 s, 5 mL min−1). Sampling rates for mixtures matched those for the individual compounds. Dissipating no energy while sampling, additional advantages of this novel device include short- or long-term sampling, high capacity and transfer efficiency for a diverse set of S/VOCs, low transfer flow rate, and a robust fabrication process.

Graphical abstract: A micro passive preconcentrator for micro gas chromatography

Supplementary files

Article information

Article type
Paper
Submitted
27 Jul 2020
Accepted
12 Sep 2020
First published
15 Sep 2020

Analyst, 2020,145, 7582-7594

Author version available

A micro passive preconcentrator for micro gas chromatography

C. Zhan, M. Akbar, R. Hower, N. Nuñovero, J. A. Potkay and E. T. Zellers, Analyst, 2020, 145, 7582 DOI: 10.1039/D0AN01485K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements