Issue 18, 2019

A high temperature optic-electric duple switching organic ionic compound: 1,4,7-triazoniacyclononane tetrafluoroborate dichloride

Abstract

[9-tacn-3]3+[BF4]2[Cl] (9-tacn-3 = 1,4,7-triazoniacyclononane), 1, is a high temperature crystal-to-crystal phase transition organic ionic compound with optic-electric duple switchable properties, mainly driven by the order–disordered changes of the cations and anions. The abundant hydrogen bonds existing in compound 1 contribute to the packing and high stability of the structure.

Graphical abstract: A high temperature optic-electric duple switching organic ionic compound: 1,4,7-triazoniacyclononane tetrafluoroborate dichloride

Supplementary files

Article information

Article type
Communication
Submitted
27 Mar 2019
Accepted
10 Apr 2019
First published
10 Apr 2019

J. Mater. Chem. C, 2019,7, 5348-5352

A high temperature optic-electric duple switching organic ionic compound: 1,4,7-triazoniacyclononane tetrafluoroborate dichloride

J. Gao, X. Hua, X. Chen and W. Liao, J. Mater. Chem. C, 2019, 7, 5348 DOI: 10.1039/C9TC01661A

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