Self-assembly growth of a multiferroic topological nanoisland array

Abstract

Ferroelectric topological configurations confined in nanostructures have attracted intensive interest both in fundamental physics and potential applications in non-volatile nanoelectronic devices. However, the preparation approaches such as chemical synthesis and template or electron beam etching inevitably induce damage and contamination; also, these are complicated processes. Herein, by a delicate design of the wetting layer and growth temperature, self-assembled ferroelectric nanoislands were achieved with the BiFeO₃/(La,Sr)MnO₃/LaAlO₃ heterostructure. Based on the thermodynamic analysis, the much lower surface energy (∼0.47 J m⁻²) of the (La,Sr)MnO₃ (∼2–12 nm)/LaAlO₃ system than that (∼1.0 J m⁻²) of BiFeO₃ provides the probability for the transformation of layered morphology into nanoislands. From the dynamic perspective, the high growth temperature (∼650–680 °C) helps to step over the energy barrier (∼50 meV per atom) by stimulating the formation of periodically arrayed dislocations at the BiFeO₃/(La,Sr)MnO₃ interface, which on the one hand releases the epitaxial elastic energy and on the other hand evokes the nucleation of the R-phase nanoisland array. More excitingly, this approach with a wonderful new growth mechanism can also be employed in other ferroelectric model systems such as BaTiO₃, which provides a new strategy for the design of novel nanoelectronic devices based on ferroelectric perovskite nanostructures.