Functionalization of [Re6Q8(CN)6]4− clusters by methylation of cyanide ligands

Maksim A. Mikhaylov; Alina D. Mironova; Konstantin A. Brylev; Taisiya S. Sukhikh; Ilia V. Eltsov; Dmitri V. Stass; Artem L. Gushchin; Noboru Kitamura; Maxim N. Sokolov

doi:10.1039/C9NJ02971K

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Functionalization of [Re₆Q₈(CN)₆]⁴⁻ clusters by methylation of cyanide ligands†

Maksim A. Mikhaylov,^a Alina D. Mironova,^a Konstantin A. Brylev,^ab Taisiya S. Sukhikh,

^ab Ilia V. Eltsov,

^b Dmitri V. Stass,^bc Artem L. Gushchin,

^ab Noboru Kitamura^d and Maxim N. Sokolov

*^ab

Author affiliations

* Corresponding authors

^a Nikolaev Institute of Inorganic Chemistry SB RAS, Prospekt Akademika Lavrentyeva 3, 630090 Novosibirsk, Russia
E-mail: caesar@niic.nsc.ru

^b Novosibirsk State University, ul. Pirogova 2, 630090 Novosibirsk, Russia

^c Voevodsky Institute of Chemical Kinetics and Combustion SB RAS, ul. Institutskaya 3, 630090 Novosibirsk, Russia

^d Department of Chemistry, Faculty of Science, Hokkaido University, 060-0810 Sapporo, Japan

Abstract

Methylation of anionic cluster complexes [Re₆Q₈(CN)₆]⁴⁻ with ((CH₃)₃O)BF₄ or CF₃SO₃CH₃ afforded homoleptic isonitrile cluster complexes [Re₆Q₈(CH₃NC)₆]²⁺ (Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry, ¹H NMR, ¹³C NMR, ¹⁴N NMR, ¹⁵N NMR, ⁷⁷Se NMR, and ¹²⁵Te NMR techniques, electrochemistry, TGA, and photophysical measurements.

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Article information

DOI: https://doi.org/10.1039/C9NJ02971K
Article type: Paper
Submitted: 07 Jun 2019
Accepted: 10 Sep 2019
First published: 11 Sep 2019

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New J. Chem., 2019,43, 16338-16348

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Functionalization of [Re₆Q₈(CN)₆]⁴⁻ clusters by methylation of cyanide ligands

M. A. Mikhaylov, A. D. Mironova, K. A. Brylev, T. S. Sukhikh, I. V. Eltsov, D. V. Stass, A. L. Gushchin, N. Kitamura and M. N. Sokolov, New J. Chem., 2019, 43, 16338 DOI: 10.1039/C9NJ02971K

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