Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)]− into [(NO)2Fe(η3-HCS2)]−via reaction with CS2

Huang-Chia Huang; Wei-Min Ching; Yu-Ting Tseng; Chien-Hong Chen; Tsai-Te Lu

doi:10.1039/C8DT04714F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Transformation of the hydride-containing dinitrosyl iron complex [(NO)₂Fe(η²-BH₄)]⁻ into [(NO)₂Fe(η³-HCS₂)]⁻via reaction with CS₂†

Huang-Chia Huang,^a Wei-Min Ching,

^b Yu-Ting Tseng,^ac Chien-Hong Chen*^d and Tsai-Te Lu

*^ae

Author affiliations

* Corresponding authors

^a Department of Chemistry, Chung Yuan Christian University, Taoyuan, Taiwan

^b Instrumentation Center, National Taiwan Normal University, Taipei, Taiwan

^c Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan

^d Department of Medical Applied Chemistry, Chung Shan Medical University and Department of Medical Education, Chung Shan Medical University Hospital, Taichung 40201, Taiwan
E-mail: cchwind@csmu.edu.tw

^e Institute of Biomedical Engineering, National Tsing Hua University, Hsinchu, Taiwan
E-mail: ttlu@mx.nthu.edu.tw

Abstract

Reaction of compounds [(NO)₂Fe(TMEDA)] and [BH₄]⁻ affords the first hydride-containing dinitrosyl iron complex (DNIC) [(NO)₂Fe(η²-BH₄)]⁻ (2). Hydride-insertion reactivity of DNIC 2 promotes the reductive transformation of CS₂ into DNIC [(NO)₂Fe(η³-HCS₂)]⁻, the first DNIC featuring both linear/bent NO ligands and Fe 3d_z²-to-HCS₂ π* backbonding interaction.

This article is part of the themed collection: Bioinspired reactivity and coordination chemistry

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C8DT04714F
Article type: Communication
Submitted: 29 Nov 2018
Accepted: 04 Jan 2019
First published: 05 Jan 2019

Download Citation

Dalton Trans., 2019,48, 5897-5902

Permissions

Request permissions

Transformation of the hydride-containing dinitrosyl iron complex [(NO)₂Fe(η²-BH₄)]⁻ into [(NO)₂Fe(η³-HCS₂)]⁻via reaction with CS₂

H. Huang, W. Ching, Y. Tseng, C. Chen and T. Lu, Dalton Trans., 2019, 48, 5897 DOI: 10.1039/C8DT04714F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions