Issue 43, 2019

Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer

Abstract

Step-scan Fourier-transform infrared spectroscopy was used to monitor the photochemical reactions following the 266 nm-photolysis of aqueous ferrioxalate solutions on microsecond-to-millisecond time scales. Together with most recent observations from ultrafast infrared spectroscopy the reported results finally disclose the full molecular-level mechanism of a photochemical system that is widely known as the Hatchard–Parker actinometer.

Graphical abstract: Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer

Article information

Article type
Communication
Submitted
23 Sep 2019
Accepted
23 Oct 2019
First published
23 Oct 2019

Phys. Chem. Chem. Phys., 2019,21, 23803-23807

Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer

F. H. Pilz, J. Lindner and P. Vöhringer, Phys. Chem. Chem. Phys., 2019, 21, 23803 DOI: 10.1039/C9CP05233J

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