Synthesis of porous coordination polymers using carbon dioxide as a direct source

Kentaro Kadota; Nghia Tuan Duong; Yusuke Nishiyama; Easan Sivaniah; Satoshi Horike

doi:10.1039/C9CC04771A

Synthesis of porous coordination polymers using carbon dioxide as a direct source†

Kentaro Kadota,

^a Nghia Tuan Duong,

^b Yusuke Nishiyama,

^bc Easan Sivaniah

^ad and Satoshi Horike

*^defg

Author affiliations

* Corresponding authors

^a Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

^b NMR Science and Development Division, RIKEN SPring-8 Center and RIKEN-JEOL Collaboration Center, Yokohama, Kanagawa 230-0045, Japan

^c JEOL RESONANCE Inc., Musashino, Akishima, Tokyo 196-8558, Japan

^d Institute for Integrated Cell-Material Sciences, Institute for Advanced Study, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: horike@icems.kyoto-u.ac.jp

^e AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL), National Institute of Advanced Industrial Science and Technology (AIST), Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501, Japan

^f Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

^g Department of Materials Science and Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong 21210, Thailand

Abstract

Porous coordination polymers (PCPs) were synthesized by using CO₂ and metal borohydrides as precursors. Borohydrides converted CO₂ into bridging ligands such as formate (HCO₂⁻) or formylhydroborate ([BH(OCHO)₃]⁻) which are available to construct porous architectures; one of them shows 380 m² g⁻¹ surface area.

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DOI: https://doi.org/10.1039/C9CC04771A
Article type: Communication
Submitted: 21 Jun 2019
Accepted: 05 Jul 2019
First published: 05 Jul 2019

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Chem. Commun., 2019,55, 9283-9286

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Synthesis of porous coordination polymers using carbon dioxide as a direct source

K. Kadota, N. T. Duong, Y. Nishiyama, E. Sivaniah and S. Horike, Chem. Commun., 2019, 55, 9283 DOI: 10.1039/C9CC04771A

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Chemical Communications

Synthesis of porous coordination polymers using carbon dioxide as a direct source†

Abstract

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Synthesis of porous coordination polymers using carbon dioxide as a direct source

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