Issue 39, 2019
From the journal:

Chemical Communications

Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions†

Ryan J. Andrews,a   Saurabh S. Chitnis ORCID logo ‡a  and  Douglas W. Stephan ORCID logo *a  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George St., Toronto, ON, Canada
E-mail: douglas.stephan@utoronto.ca

Abstract

The readily-accessible, air-stable Lewis acid [(terpy)PPh][B(C6F5)4]21 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The utility and mechanism of these hydrosilylations are considered.

Graphical abstract: Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions

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Article information

DOI
https://doi.org/10.1039/C9CC02460C
Article type
Communication
Submitted
29 Mar 2019
Accepted
16 Apr 2019
First published
16 Apr 2019

Chem. Commun., 2019,55, 5599-5602

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Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(III) dication under mild conditions

R. J. Andrews, S. S. Chitnis and D. W. Stephan, Chem. Commun., 2019, 55, 5599 DOI: 10.1039/C9CC02460C

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