Issue 42, 2019

Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy)2(bpz)2+ complex: implications for photoinduced electron–proton transfer

Abstract

The equilibrium constants of the hydrogen bonding (HB) between hydroxylic donors, ROH, and an MLCT-excited Ru(bpy)2(bpz)2+ complex, 1(T), correlated with ROH empirical HB acidities, which could be used for evaluating the unimolecular rate constants of concerted electron–proton transfer within the H-bonded phenol–1(T) exciplexes.

Graphical abstract: Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy)2(bpz)2+ complex: implications for photoinduced electron–proton transfer

Supplementary files

Article information

Article type
Communication
Submitted
08 Mar 2019
Accepted
16 Apr 2019
First published
16 Apr 2019

Chem. Commun., 2019,55, 5870-5873

Author version available

Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy)2(bpz)2+ complex: implications for photoinduced electron–proton transfer

S. V. Lymar, G. F. Manbeck and D. E. Polyansky, Chem. Commun., 2019, 55, 5870 DOI: 10.1039/C9CC01896D

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