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A squaramide-decorated COF was synthesized and used as a highly efficient heterogeneous catalyst for hydrogen-bonding organocatalysis as exemplified in the context of catalyzing Michael addition reactions under mild conditions. Our work lays a foundation for the development of functional COFs as a new platform for biomimetic organocatalysis.

Graphical abstract: Squaramide-decorated covalent organic framework as a new platform for biomimetic hydrogen-bonding organocatalysis

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