Yawei Duana,
Jingge Fenga,
Youyi Zhub,
Hongda Lia,
Xintong Liua,
Hualei Zhou*a and
Wenjun Lia
aBeijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, University of Science and Technology Beijing, Beijing 100083, China. E-mail: hlzhou@ustb.edu.cn
bResearch Institute of Petroleum Exploration and Development, China National Petroleum Corporation, Beijing 100083, China
First published on 15th November 2018
Petroleum sulfonates are broadly employed to increase the oil recovery efficiency in tertiary recovery, while the content of di-sulfonates in petroleum sulfonates is a critical factor in the flushing efficiency, because it adversely impacts the decrease of oil-water interfacial tension. Thus far, no methods have been considered convenient and reliable to determine the contents of mono- and di-sulfonates besides the traditional extraction method. This study established a simple and practical approach of acid–base titration coupled with traditional two-phase titration to measure the contents of mono- and di-sulfonates in petroleum sulfonates. To judge the reliability of the approach, the actives of petroleum sulfonates were separated into mono- and di-sulfonates using the traditional extraction method, the separation effect of which was confirmed using infrared spectroscopy and main elemental analysis. As the results demonstrated, all the contents of di-sulfonates in four petroleum sulfonates measured by the acid–base titration method are similar to those found by the extraction method. The contents of di-sulfonates (%) in four petroleum sulfonate samples were measured by comparing acid–base titration with the extraction method; respectively they were 8.57/8.19, 5.67/5.98, 5.61/5.35 and 2.37/2.15; the relative error of the measured di-sulfonates is about 6%, which satisfies the titration accuracy of petroleum sulfonates. In parallel experiments, the results of five acid–base titrations are very close, and the precision of the acid–base titration method was about 3%. Accordingly, this systematic approach by combining the new acid–base titration and traditional two-phase titration is of great significance to develop the evaluation system of petroleum sulfonates.
Petroleum sulfonates originate from the sulfonation of aromatic crude oil distillate or furfural dewaxing oil distillate.16 The obtained crude products basically fall into four components, i.e., volatile components, inorganic salt, unsulfonated oil and actives.17–19 Up to now, there are two main methods for evaluating petroleum sulfonates, one is the gravimetric method and the other is the two-phase titration method.20,21 Nevertheless, these two methods can only measure the contents of actives, while the contents of mono- and di-sulfonates in petroleum sulfonates cannot be accurately measured. For further evaluating the petroleum sulfonates, the actives of petroleum sulfonates are considered consisting of mono-sulfonates, di-sulfonates and poly-sulfonates; generally, the di-sulfonates and poly-sulfonates are collectively called di-sulfonates as the amount of poly-sulfonates is rather small.22 In petroleum sulfonates, mono-sulfonates play a major role in decreasing interfacial tension of oil-water.23 On the contrary, di-sulfonates in petroleum sulfonate could adversely impact the decrease of interfacial tension of oil–water; also, it occupies the contents of the practical active substance in petroleum sulfonates, and then affects the oil displacement effect.23 It is well-known that the traditional extraction method can be used to directly separate and achieve the mono- and di-sulfonates from the petroleum sulfonates;24 nevertheless, this method needs to take a large amount of time (3–4 days) to complete a whole separation process by using high-dose organic solvents. Additionally, HPLC is inappropriate for evaluating the petroleum sulfonates, because the standard sample as a reference is unavailable due to much more complex composition of petroleum sulfonates, though some studies reported that was applied for the detection of mono- and di-sulfonates.25,26 Accordingly, it is of great significance to explore a rapid and pollution-free approach to ultimately determine the contents of mono- and di-sulfonates in petroleum sulfonates.
The interaction of two adjacent sulfonate radicals in a conjugated pi bond of di-sulfonates may decrease the acidity of the one of the sulfonate radicals; pH titration may serve as a very simple and rapid method to detect the contents of weak acid ions. In this work, the contents of di-sulfonates in petroleum sulfonates can be measured given that the pH change of the binary weak acid ions will be abrupt after the first complete hydrolysis. Then, the content of mono-sulfonates could be calculated by the difference between the contents of actives by traditional two-phase titration and di-sulfonates by acid–base titration. The approach of acid–base titration coupled with two-phase titration gives a novel strategy to systematically evaluate the oil displacement performance of petroleum sulfonates by determining the contents of mono- and di-sulfonates in petroleum sulfonates.
Then the actives solution was changed into petroleum sulfonates solution, repeating the above steps, and calculated the contents of the active substances in the sample by the formula.
Fig. 1 Separation process of petroleum sulfonates.24,27 |
Then, the desalination samples were dissolved with 50 mL mixed solvent (50% isopropanol/water, volume ratio), and transferred into a separatory funnel. The dissolved mixtures were repeatedly extracted with n-pentane until the supernatant turns into yellowish, and the lower liquid was collected. Then, the back extraction was performed. The actives appeared in the lower liquid, and the unsulfonated oil appeared in the upper liquid.
Finally, the obtained actives were extracted with 1:1 n-butanol/water, and the lower liquid was extracted continuously and repeatedly by the same extraction agent. The di-sulfonates appeared in the lower liquid and the mono-sulfonates appeared in the upper liquid.
Components | The mass fraction/% | The recovery rate/% |
---|---|---|
Volatile | 22.38 | 98.37 |
Inorganic salt | 9.04 | |
Unsulfated oil | 37.41 | |
Mono-sulfonates | 21.35 | |
Di-sulfonates | 8.19 |
To detect the structural property, infrared spectra of mono-sulfonates, di-sulfonates and active samples were determined with the same quality. Fig. 2 shows that the peaks at 1047 and 1195 cm−1 were symmetric stretching vibration and asymmetric stretching vibration of the SO bond of sulfonate. The peaks close to 1458 cm−1 were an asymmetric deformation vibration and symmetric deformation vibration of –CH3. The peaks at 1635 cm −1 were stretching vibration for the CC bond. The asymmetric stretching vibrations of –CH2– and –CH3 were peaked at 2858 and 2937 cm−1. As the results suggest, both the infrared spectra of actives, mono-sulfonates and di-sulfonates take on the characteristic peaks at 1047 and 1195 cm−1 of sulfonic acid groups, yet the intensity of characteristic peaks for di-sulfonates are obviously higher than that of mono-sulfonates. The intensity of di-sulfonates was almost 1.7 times that of mono-sulfonates at the characteristic peaks of sulfonic acid groups (1047 and 1195 cm−1). This suggests the effective separation of mono- and di-sulfonates.
Fig. 2 Infrared spectra of the actives, separated mono-sulfonates and enriched di-sulfonates from sample 1. |
To further confirm the effect of separation and enrichment, elemental analysis was employed to measure the contents of C, H and S in mono-sulfonates, di-sulfonates and actives, respectively. It is suggested that the element distribution of mono-sulfonates and actives is very similar, yet the relative contents of sulfur element in di-sulfonates is obviously higher than that of actives and mono-sulfonates. Both the results of infrared spectra and elemental analysis prove that mono- and di-sulfonates have been effectively separated (Table 2).
Elements components | C (%) | H (%) | S (%) |
---|---|---|---|
Mono-sulfonates | 60.18 | 7.724 | 8.059 |
Di-sulfonates | 55.15 | 5.715 | 14.078 |
Actives | 57.22 | 6.907 | 8.374 |
Fig. 3B is the first-order derivative of Fig. 3A, where the two minimal values of the first derivative corresponding to the stoichiometric points. And the amount of the reacted part in the sample can be calculated by referencing the difference between the two minimal values. When the titrated di-sulfonates solution was at the middle of the two stoichiometric points (semi-metering point), equivalent amount of salt and weak acid was ionized, i.e., the amount of A2− ion were the same as that of HA− presenting in the solution when pKa2 = pH. Accordingly, the pKa2 value of the di-sulfonates in the sample can be acquired from the semi-metering point as above.
The content of di-sulfonates in enriched di-sulfonates samples could be calculated by the follow formula.
In this experiment, the concentration of dilute hydrochloric acid and enriched di-sulfonates solution were 4.32 × 10−2 mol L−1 (C2) and 6.11 g L−1 (C1) (with the dosage of 10 mL (V1)), respectively. Thus, the mass of enriched di-sulfonates samples was 0.0611 g. And the titrimetric volume of reacting dilute hydrochloric acid was 2.205 mL (V2). Thus, the amount of di-sulfonates can be calculated as 9.526 × 10−5 mol, and the contents of di-sulfonates as 1.559 × 10−3 mol g−1. Given the average equivalent weight of di-sulfonates as 550 g mol−1 (Md),32,33 the titrimetric di-sulfonates mass was 5.2393 × 10−2 g. Therefore, the calculated contents of di-sulfonates in enriched di-sulfonates samples was 85.75%, which directly suggests that di-sulfonates have been effectively enriched.
Fig. 5 shows that the titration curve of mono-sulfonates by acid–base titration from sample 1, which displayed merely one jump under the same titration conditions. Thus, the contents of mono-sulfonates cannot be measured by acid–base titration, which could dissatisfy the condition with obvious jump (cKb > 10−8) and the isolated mono-sulfonates had high purity with just a few di-sulfonates.
Unsulfonated oil was added to the di-sulfonates solution, and then it fell into two phases instantly with no distribution of the unsulfonated oil in the water phase. As a result, the titration process was not affected.
As listed in Table 3, the contents of titrant and di-sulfonates in the titration system were respectively 4.32 × 10−2 mol L−1 and 6.11 g L−1 (10 mL), and the mass ratios of mono-sulfonates to di-sulfonates were nearly 1:5, 1:1 and 2:1, respectively. After the addition of a certain proportion of mono-sulfonates, the consumption of dilute hydrochloric acid titrant remained unchanged, thus suggesting that the mono-sulfonates did not influence the titration of the di-sulfonates within a certain range. The main ions in petroleum sulfonates primarily included Na+, SO42−, Cl− and very small amounts of Ca2+, Mg2+ and NO3−, thus Na2SO4 and NaCl were selected in a mass ratio of 10:1 as the representatives to investigate the effect of the different amounts of inorganic salt on the titration of di-sulfonates. The contents of di-sulfonates in the titration system remained 6.11 g L−1 (10 mL), and the mass ratio of inorganic salt to enriched di-sulfonates was nearly 1:5, 1:1 and 2:1. Similarly, the consumption of titrant has hardly changed.
Amount of added mono-sulfonates/×10−2 g | Consumption of titrant per mL | Amount of added inorganic salt/10−2 g | Consumption of titrant per mL |
---|---|---|---|
0 | 2.207 | 0 | 2.207 |
1.22 | 2.211 | 1.22 | 2.209 |
6.11 | 2.214 | 6.11 | 2.205 |
12.22 | 2.216 | 12.22 | 2.212 |
No | 1 | 2 | 3 | 4 | 5 |
---|---|---|---|---|---|
• The consumed volumes of titrant (mL) | 1.719 | 1.701 | 1.742 | 1.780 | 1.646 |
• The contents of di-sulfonates (mol g−1) | 1.559 × 10−4 | 1.543 × 10−4 | 1.580 × 10−4 | 1.614 × 10−4 | 1.493 × 10−4 |
• The contents of di-sulfonates measured by titration (%) | 8.57 | 8.48 | 8.70 | 8.88 | 8.21 |
• RSD (%) | 2.9 |
The possible causes of the experimental errors are as follows: (1) the carbon dioxide in the air may participate in the reaction as a weak acid. Thus the containers were sealed with sealing film, to ultimately eliminate the effect of carbon dioxide to the greatest extent. (2) As the equivalent point cannot be predicted accurately, and the titrant can be merely added at a constant speed during the titration. Accordingly, there may be an error of half a drop in the titrant volume corresponding to the leaps, yet the error can be eliminated by parallel experiment.
The percentage contents of di-sulfonates of four petroleum sulfonate samples were measured using acid–base titration and extraction method, respectively. The contents of di-sulfonates (the average molecular weight was taken as 550 g mol−1) and the corresponding pKa2 values of four petroleum sulfonates were obtained by conducting differential calculation, as listed in Table 5. Obviously, the relative errors of measured di-sulfonates in four petroleum sulfonate samples were 4.64%, −5.18%, 4.86% and 10.23%, respectively. Sample 1 had the highest contents of di-sulfonates and complied with the characteristic titration curve of weak acid, while sample 4 had the lowest contents of di-sulfonates, and the pKa2 value was much lower than that of the other three ones. This may be attributed to the rather low contents of di-sulfonates in sample 4, and the small titration volume consequently increases the titration error. The contents of actives measured by two-phase titration were 26.59%, 23.66%, 35.73% and 25.07%, respectively. Furthermore, the contents of mono-sulfonates in four petroleum sulfonates can be calculated by the difference between the contents of actives via two-phase titration and di-sulfonates via acid–base titration, respectively were 18.02%, 17.99%, 30.12% and 22.70%. In sample 3 and 4, the content of mono-sulfonates was almost 6 and 10 times that of di-sulfonates, respectively. More mono-sulfonates will be favorable for EOR (enhanced oil recovery), due to mono-sulfonates in petroleum sulfonates play a major role in decreasing interfacial tension of oil-water.23 Accordingly, both the contents of mono- and di-sulfonates in petroleum sulfonates can be estimated by the approach of the acid–base titration coupled with two-phase titration.
Samples | 1 | 2 | 3 | 4 |
---|---|---|---|---|
• The contents of di-sulfonates measured by separation (%) | 8.19 | 5.98 | 5.35 | 2.15 |
• The contents of di-sulfonates measured by acid–base titration (%) | 8.57 | 5.67 | 5.61 | 2.37 |
• pKa2 of acid–base titration | 6.74 | 6.49 | 6.68 | 5.95 |
• Relative error of acid–base titration (%) | 4.64 | −5.18 | 4.86 | 10.23 |
• The contents of actives measured by two-phase titration (%) | 26.59 | 23.66 | 35.73 | 25.07 |
• The contents of mono-sulfonates (%) | 18.02 | 17.99 | 30.12 | 22.70 |
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