CuAAC click chemistry: a versatile approach towards PVDF-based block copolymers

I. Terzic; N. L. Meereboer; K. Loos

doi:10.1039/C8PY00742J

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CuAAC click chemistry: a versatile approach towards PVDF-based block copolymers†

I. Terzic,^a N. L. Meereboer^a and K. Loos

*^a

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* Corresponding authors

^a Macromolecular Chemistry and New Polymeric Materials, Zernike Institute for Advanced Materials, University of Groningen, The Netherlands
E-mail: k.u.loos@rug.nl

Abstract

Alkyne/azide end terminated PVDF homopolymers were synthesized via free-radical polymerization using functional benzoyl peroxides as initiators. This approach allows the preparation of PVDF triblock copolymers with various functional blocks (polystyrene, poly(N-isopropylacrylamide) and poly(tert-butyl acrylate)) and tunable crystallization behavior using copper(I)-catalyzed azide–alkyne cyclo-addition.

This article is part of the themed collection: Bioorthogonal and click chemistry: Celebrating the 2022 Nobel Prize in Chemistry

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DOI: https://doi.org/10.1039/C8PY00742J
Article type: Communication
Submitted: 17 May 2018
Accepted: 24 Jun 2018
First published: 25 Jun 2018

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Polym. Chem., 2018,9, 3714-3720

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CuAAC click chemistry: a versatile approach towards PVDF-based block copolymers

I. Terzic, N. L. Meereboer and K. Loos, Polym. Chem., 2018, 9, 3714 DOI: 10.1039/C8PY00742J

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Polymer Chemistry

CuAAC click chemistry: a versatile approach towards PVDF-based block copolymers†

Abstract

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CuAAC click chemistry: a versatile approach towards PVDF-based block copolymers

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