Fei Ling, Lian Xiao, Lu Fang, Cong Feng, Zhen Xie, Yaping Lv and Weihui Zhong
Org. Biomol. Chem., 2018,16, 9274-9278
DOI:
10.1039/C8OB02805B,
Paper
The first example of the metal- and solvent-free B(C6F5)3-catalyzed Markovnikov addition of indoles to aryl alkynes was disclosed. Both N–H and N-protected indoles were tolerated, leading to a wide spectrum of versatile bis(indolyl)alkanes in moderate to good yields with high regioselectivities.