Synthesis of fluoroalkylated alkynes via visible-light photocatalysis

Naila Iqbal; Naeem Iqbal; Sung Su Han; Eun Jin Cho

doi:10.1039/C8OB02486C

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Synthesis of fluoroalkylated alkynes via visible-light photocatalysis†

Naila Iqbal,^a Naeem Iqbal,^a Sung Su Han^a and Eun Jin Cho

*^a

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* Corresponding authors

^a Department of Chemistry, Chung-Ang University, 84 Heukseok-ro, Dongjak-gu, Seoul 06974, Republic of Korea
E-mail: ejcho@cau.ac.kr

Abstract

Fluoroalkylated alkynes, which are versatile building blocks for the synthesis of various biologically active organofluorine compounds, were synthesized from easily available alkynyl halides and fluoroalkyl halides by visible-light photocatalysis. Addition of fluoroalkyl radicals to alkynes and subsequent dehalogenation selectively yielded fluoroalkylated alkynes.

This article is part of the themed collections: Synthetic methodology in OBC and New Talent

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Article information

DOI: https://doi.org/10.1039/C8OB02486C
Article type: Communication
Submitted: 06 Oct 2018
Accepted: 06 Nov 2018
First published: 07 Nov 2018

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Org. Biomol. Chem., 2019,17, 1758-1762

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Synthesis of fluoroalkylated alkynes via visible-light photocatalysis

N. Iqbal, N. Iqbal, S. S. Han and E. J. Cho, Org. Biomol. Chem., 2019, 17, 1758 DOI: 10.1039/C8OB02486C

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Organic & Biomolecular Chemistry

Synthesis of fluoroalkylated alkynes via visible-light photocatalysis†

Abstract

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Synthesis of fluoroalkylated alkynes via visible-light photocatalysis

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