A glycoluril dimer–triptycene hybrid receptor: synthesis and molecular recognition properties

Wenjin Liu; Xiaoyong Lu; Zihui Meng; Lyle Isaacs

doi:10.1039/C8OB01575A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A glycoluril dimer–triptycene hybrid receptor: synthesis and molecular recognition properties†

Wenjin Liu,‡^ab Xiaoyong Lu,‡^b Zihui Meng

*^a and Lyle Isaacs

*^b

Author affiliations

* Corresponding authors

^a School of Chemistry and Chemical Engineering, Beijing Institute of Technology, 5 South Zhongguancun Street, Beijing 100081, P. R. China

^b Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA
E-mail: lisaacs@umd.edu

Abstract

The strategic combination of the methylene bridged glycoluril dimer and triptycene skeletons delivers acyclic water soluble hybrid receptor 1 which is analogous to cucurbit[6]uril. The molecular recognition properties of host 1 toward hydrophobic cationic guests are investigated in detail by a combination of ¹H NMR spectroscopy and isothermal titration calorimetry (ITC) studies. The fluorescence emission of 1 can be selectively and efficiently quenched upon the formation of 1·26 and 1·28 complexes.

This article is part of the themed collection: Supramolecular chemistry in OBC

Download options Please wait...

Supplementary files

Supplementary information PDF (11834K)

Article information

DOI: https://doi.org/10.1039/C8OB01575A
Article type: Paper
Submitted: 04 Jul 2018
Accepted: 19 Aug 2018
First published: 23 Aug 2018

Download Citation

Org. Biomol. Chem., 2018,16, 6499-6506

Author version available

Download author version (PDF)

Permissions

Request permissions

A glycoluril dimer–triptycene hybrid receptor: synthesis and molecular recognition properties

W. Liu, X. Lu, Z. Meng and L. Isaacs, Org. Biomol. Chem., 2018, 16, 6499 DOI: 10.1039/C8OB01575A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Organic & Biomolecular Chemistry

A glycoluril dimer–triptycene hybrid receptor: synthesis and molecular recognition properties†

Abstract

Supplementary files

Article information

Download Citation

Author version available

Permissions

A glycoluril dimer–triptycene hybrid receptor: synthesis and molecular recognition properties

Social activity

Search articles by author

Spotlight

Advertisements