Na3Ca4(TeO3)(PO4)3: a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance

Zhuang Li; Shengzi Zhang; Wenlong Yin; Zheshuai Lin; Jiyong Yao; Yicheng Wu

doi:10.1039/C8DT04354J

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Na₃Ca₄(TeO₃)(PO₄)₃: a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance†

Zhuang Li,^abc Shengzi Zhang,^ac Wenlong Yin,^d Zheshuai Lin,^a Jiyong Yao

*^ab and Yicheng Wu^ae

Author affiliations

* Corresponding authors

^a Beijing Center for Crystal Research and Development, Key Lab of Functional Crystals and Laser Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: jyao@mail.ipc.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

^c University of Chinese Academy of Sciences, Beijing 100049, P. R. China

^d Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, People's Republic of China

^e Institute of Functional Crystal Materials, Tianjin University of Technology, Tianjin 300384, P.R. China

Abstract

A new functional compound Na₃Ca₄(TeO₃)(PO₄)₃ has been successfully synthesized and fully characterized. It is the first example of a tellurite phosphate that exhibits a fascinating multimember-ring configuration. Moreover, a careful theoretical and experimental study also reveals the intriguing nonlinear optical performance of Na₃Ca₄(TeO₃)(PO₄)₃.

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Article information

DOI: https://doi.org/10.1039/C8DT04354J
Article type: Communication
Submitted: 01 Nov 2018
Accepted: 19 Nov 2018
First published: 19 Nov 2018

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Dalton Trans., 2018,47, 17198-17201

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Na₃Ca₄(TeO₃)(PO₄)₃: a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance

Z. Li, S. Zhang, W. Yin, Z. Lin, J. Yao and Y. Wu, Dalton Trans., 2018, 47, 17198 DOI: 10.1039/C8DT04354J

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