Synthesis and properties of heterobimetallic rhodium complexes featuring LiI, CuI or ZnII as a Lewis acidic metalloligand

Patrick Steinhoff; Ralf Steinbock; Anna Friedrich; Benjamin G. Schieweck; Christopher Cremer; Khai-Nghi Truong; Michael E. Tauchert

doi:10.1039/C8DT01267A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Synthesis and properties of heterobimetallic rhodium complexes featuring Li^I, Cu^I or Zn^II as a Lewis acidic metalloligand†

Patrick Steinhoff,^a Ralf Steinbock,^a Anna Friedrich,^a Benjamin G. Schieweck,^a Christopher Cremer,

^a Khai-Nghi Truong

^a and Michael E. Tauchert

*^a

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1A, D-52074 Aachen, Germany
E-mail: Michael.Tauchert@ac.rwth-aachen.de

Abstract

A series of [(PMP)Rh(CO)Cl]ⁿ⁺ complexes was synthesised and the impact of the metalloligands Cu^I, Li^I and Zn^II on the CO stretching band was analysed.

This article is part of the themed collection: New Talent: Europe

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C8DT01267A
Article type: Communication
Submitted: 31 Mar 2018
Accepted: 05 Jul 2018
First published: 13 Jul 2018

Download Citation

Dalton Trans., 2018,47, 10439-10442

Permissions

Request permissions

Synthesis and properties of heterobimetallic rhodium complexes featuring Li^I, Cu^I or Zn^II as a Lewis acidic metalloligand

P. Steinhoff, R. Steinbock, A. Friedrich, B. G. Schieweck, C. Cremer, K. Truong and M. E. Tauchert, Dalton Trans., 2018, 47, 10439 DOI: 10.1039/C8DT01267A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions