Supramolecular self-assembly of heterobimetallic complexes: a new N,P-based, selective heteroditopic ligand

Abstract

Pyrimidine-hydrazone and phosphole architectures have been combined to create a new heteroditopic ligand capable of forming heterobimetallic Zn^II/Pd^II, Pb^II/Pd^II and Cu^II/Pd^II complexes in high yielding stepwise or one pot reactions. The catalytic activity of these complexes in Heck coupling and Miyaura borylation reactions was investigated.