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Correction: Conceptual design and analysis of ITM oxy-combustion power cycles

Andrea König a, Nick D. Mancini b and Alexander Mitsos *b
aAachener Verfahrenstechnik – Process Systems Engineering, RWTH Aachen University, Forckenbeckstr. 51, 52074 Aachen, Germany
bDepartment of Mechanical Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue (MIT 3-158), Cambridge, MA 02139, USA. E-mail: amitsos@alum.mit.edu; Fax: +1 (617)-258-5802; Tel: +1 (617)-324-6768

Received 15th November 2018 , Accepted 15th November 2018

First published on 23rd November 2018


Abstract

Correction for ‘Conceptual design and analysis of ITM oxy-combustion power cycles’ by N. D. Mancini et al., Phys. Chem. Chem. Phys., 2011, 13, 21351–21361.


In ref. 1 Mancini and Mitsos simulated a variety of ion transport membrane (ITM) power cycles. The authors discussed the benefits of partial emissions cycles over a combination of zero-emissions cycles and conventional combined cycles using a linear combination metric.

Ref. 1 presented the linear combination of the zero-emissions cycle and conventional combined cycle as a line in a graph, i.e., Fig. 8 of ref. 1 with First Law Efficiency and CO2 emissions as evaluation criteria. Ref. 1 thus implied that the First Law Efficiency of a linear combination of non-hybrid plants can be determined by simple linear interpolation of the efficiencies of each non-hybrid plant, i.e.,

 
image file: c8cp91924k-t1.tif(1)
with λ being the plant split fraction, which is based on the output of each cycle type, i,
 
image file: c8cp91924k-t2.tif(2)

It can be seen that ηlincom,incorrect is not equivalent to the overall First Law Efficiency, image file: c8cp91924k-t3.tif. Instead, one should use a reverse linear interpolation. Then out,i is canceled out, such that the overall First Law Efficiency of the linear combination is correctly determined,

 
image file: c8cp91924k-t4.tif(3)

Ref. 1 correctly used a linear interpolation for the second performance criterion, i.e., CO2 emissions. This leads to an inverse relationship of the two performance criteria, i.e.,

 
image file: c8cp91924k-t5.tif(4)

Based on this insight, Fig. 1 shows how the performance line of Fig. 8 in ref. 1 has to be amended.


image file: c8cp91924k-f1.tif
Fig. 1 Corrected linear combination originally from ref. 1.

When comparing the corrected function to the line originally illustrated in ref. 1 it becomes clear that the actual performance of a linear combination is slightly worse than previously indicated. Thus, from a relative perspective, partial emission cycles perform slightly better than previously thought.

In conclusion, the application of the linear combination in ref. 1 is incorrect but results in very small numerical errors.

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.

References

  1. N. D. Mancini and A. Mitsos, Phys. Chem. Chem. Phys., 2011, 13, 21351–21361 RSC.

Footnote

Present address: Tesla Inc., 3500 Deer Creek Rd., Palo Alto, CA 94304, USA.

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