Probing the in-air growth of large area of 3D functional structures into a 2D supramolecular nanoporous network

Romain Brisse; Dominique Guianvarc'h; Christelle Mansuy; Sandrine Sagan; David Kreher; Lydia Sosa-Vargas; Lydia Hamitouche; Vincent Humblot; Imad Arfaoui; Vanessa Labet; Céline Paris; Christophe Petit; André-Jean Attias

doi:10.1039/C8CC06125D

Probing the in-air growth of large area of 3D functional structures into a 2D supramolecular nanoporous network†

Romain Brisse,

^abc Dominique Guianvarc'h,

^b Christelle Mansuy,

^b Sandrine Sagan,

^b David Kreher,^a Lydia Sosa-Vargas,

^a Lydia Hamitouche,^a Vincent Humblot,

^d Imad Arfaoui,

^c Vanessa Labet,

^c Céline Paris,^c Christophe Petit

*^c and André-Jean Attias

*^ae

Author affiliations

* Corresponding authors

^a IPCM, UMR CNRS-Sorbonne Université 8232, 4 Place Jussieu, 75005 Paris, France
E-mail: andre-jean.attias@sorbonne-universite.fr

^b Sorbonne Université, École Normale Supérieure, PSL University, CNRS, Laboratoire des biomolécules, LBM, 75005 Paris, France

^c MONARIS, UMR CNRS-Sorbonne Université 8233, 4 Place Jussieu, 75005 Paris, France
E-mail: christophe.petit@sorbonne-université.fr

^d LRS, UMR CNRS-Sorbonne Université 7197, 4 Place Jussieu, 75005 Paris, France

^e UMI Building Blocks for Future Electronics, CNRS – Sorbonne Université – Yonsei University – Ewha Womans University, 50 Yonsei-ro Seodaemun-gu, Seoul, Korea
E-mail: aj-attias@yonsei.ac.kr

Abstract

Surface-confined host–guest chemistry at the air/solid interface is used for trapping a functionalized 3D Zn–phthalocyanine complex into a 2D porous supramolecular template allowing the large area functionalization of an sp²-hybridized carbon-based substrate as evidenced by STM, resonance Raman spectroscopy, and water contact angle measurements.

This article is part of the themed collection: Scanning probe frontiers in molecular 2D-architecture world

Chemical Communications

Probing the in-air growth of large area of 3D functional structures into a 2D supramolecular nanoporous network†

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Probing the in-air growth of large area of 3D functional structures into a 2D supramolecular nanoporous network

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