Impact of partial interpenetration in a hybrid ultramicroporous material on C2H2/C2H4 separation performance

Daniel O’Nolan; David G. Madden; Amrit Kumar; Kai-Jie Chen; Tony Pham; Katherine A. Forrest; Ewa Patyk-Kazmierczak; Qing-Yuan Yang; Claire A. Murray; Chiu C. Tang; Brian Space; Michael J. Zaworotko

doi:10.1039/C8CC01627E

Impact of partial interpenetration in a hybrid ultramicroporous material on C₂H₂/C₂H₄ separation performance†

Daniel O’Nolan,

^a David G. Madden,

^a Amrit Kumar,^a Kai-Jie Chen,^a Tony Pham,

^b Katherine A. Forrest,^b Ewa Patyk-Kazmierczak,^a Qing-Yuan Yang,^a Claire A. Murray,^c Chiu C. Tang,^c Brian Space

^b and Michael J. Zaworotko

*^a

Author affiliations

* Corresponding authors

^a Bernal Institute, Department of Chemical Sciences, University of Limerick, Limerick, Ireland
E-mail: xtal@ul.ie

^b Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, Florida 33620, USA

^c Diamond Light Source Ltd, Harwell Science and Innovation Campus, Didcot, Oxfordshire, UK

Abstract

Phases of a 2-fold pcu hybrid ultramicroporous material (HUM), SIFSIX-14-Cu-i, exhibiting 99%, 93%, 89%, and 70% partial interpenetration have been obtained. 1 : 99 C₂H₂/C₂H₄ gas separation studies reveal that as the proportion of interpenetrated component decreases, so does the separation performance.

Chemical Communications

Impact of partial interpenetration in a hybrid ultramicroporous material on C₂H₂/C₂H₄ separation performance†

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Impact of partial interpenetration in a hybrid ultramicroporous material on C₂H₂/C₂H₄ separation performance

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