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Cadmium ion-enhanced photochemical vapour generation directly from Se(VI) has for the first time been reported here, and the key mechanism of the in situ formation of nano-CdSe as a photocatalyst has been revealed.

Graphical abstract: In situ formation of nano-CdSe as a photocatalyst: cadmium ion-enhanced photochemical vapour generation directly from Se(vi)

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