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Ultrasmall (10.8 nm) and uniform hexagonal NaYF4:Yb3+,Er3+ upconversion nanocrystals have been successfully synthesized through a temperature oscillation technique, and the nucleation and growth processes of nanocrystals were effectively separated and controlled by simply regulating the heating procedures.

Graphical abstract: Facile synthesis of ultrasmall hexagonal NaYF4:Yb3+,Er3+ upconversion nanocrystals through temperature oscillation

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