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Photosensitizers play a crucial role in p-type dye-sensitized solar cells (p-DSSCs). In this study, we first introduced two Dawson-type transition metal-substituted polyoxometalate dyes to co-sensitize the NiO electrode and achieved an overall power conversion efficiency (PCE) of 0.0464%, which is the highest value reported for inorganic photosensitizers in p-DSSCs.

Graphical abstract: Low-cost p-type dye-sensitized solar cells based on Dawson-type transition metal-substituted polyoxometalate inorganic co-sensitizers

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