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Abstract | Cited by

From the viewpoint of mathematics and topology, we proposed a rational design and stabilized the first five-fold interpenetrated porous coordination polymer (PCP) with a pcu topology and extra-framework volume (60.0%) by employing a linear ligand with the length of ∼2 nm. The resulting compound exhibits good CO2 uptake, enabling highly selective separation of CO2 from CO2/CO mixtures.

Graphical abstract: Pre-design and synthesis of a five-fold interpenetrated pcu-type porous coordination polymer and its CO2/CO separation

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