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The polydimethylsiloxane (PDMS) coating penetrated into the underneath ZIF-8 polycrystalline membrane not only blocking the inter-crystalline defects but also hindering the flexibility of the ZIF-8 framework, resulting in an unusual and highly desired increase in the separation selectivity of the C3H6/C3H8 mixture under high feeding pressures.

Graphical abstract: Enhanced C3H6/C3H8 separation performance on MOF membranes through blocking defects and hindering framework flexibility by silicone rubber coating

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