A. C. Yanga,
S. S. Yana,
K. Zhanga,
H. H. Lia,
J. Peia,
L. M. Hea,
Y. F. Tiana,
Y. F. Qinb,
S. S. Kanga and
S. Q. Xiao*a
aSchool of Physics, State Key Laboratory of Crystal Materials, Shandong University, Jinan, Shandong 250100, People's Republic of China. E-mail: xsq@sdu.edu.cn
bDepartment of Applied Physics, School of Information Science and Engineering, Shandong Agricultural University, Taian, Shandong 271018, People's Republic of China
First published on 25th May 2016
Rashba spin–orbit coupling, which allows the manipulation of electron spins in semiconductor heterostructures, has attracted great interest due to its potential applications in spintronic devices. But it is still not clear whether the Rashba spin–orbit coupling in a p–n junction can have a significant effect on the anomalous Hall effect of a p-type ferromagnetic semiconductor film grown on an n-type semiconductor substrate. Here MnxSi1−x/SiO2/Si p–i–n junctions were formed by sputtering p-type MnxSi1−x magnetic semiconductor films on near-intrinsic n-type Si substrates with about 1 nm SiO2 native oxide layer. Although Mn0.48Si0.52/SiO2/Si p–i–n junctions and Mn0.48Si0.52 magnetic semiconductor films grown on insulating glass substrates almost show the same positive anomalous Hall effect at low temperature below 150 K, Mn0.48Si0.52/SiO2/Si p–i–n junctions show a greatly enhanced negative anomalous Hall effect around the temperature of 200 K. On further analysis of the in-plane resistance of Mn0.48Si0.52 films and the I–V curves of the p–i–n junctions, the enhanced negative anomalous Hall effect is attributed to the interfacial Rashba spin–orbit coupling in Mn0.48Si0.52/SiO2/Si p–i–n junctions.
Recently, the SOC and/or AHE have been extensively studied in many heterojunction systems such as the oxide interface of LaAlO3/SrTiO3,18,19 the Ge space-charge layer in Pb/Ge,20 and a modulation-doped single quantum well,21 where the SOC or AHE was even greatly tuned by the gate-voltage18,21 and electrical current.19 But a more common case is a p–n junction which is formed at the interface when a p-type ferromagnetic semiconductor film is grown on an n-type semiconductor substrate. The strong built-in electrical field in the p–n junction may produce very strong Rashba spin–orbit coupling. Moreover, the potential or electrical field of the p–n junction can be easily tuned by the applied voltage, carrier density, inserted insulating layer, temperature and so on. However, we do not know whether the Rashba spin–orbit coupling in the p–n junction can have a significant effect on the AHE of the p-type ferromagnetic semiconductor films grown on the n-type semiconductor substrates.
In this paper, we report that MnxSi1−x/SiO2/Si p–i–n junctions, which were formed by sputtering p-type MnxSi1−x magnetic semiconductor films on near-intrinsic n-type Si substrates with about 1 nm SiO2 native oxide layer, show greatly enhanced negative anomalous Hall effect around the temperature of 200 K, although the same MnxSi1−x magnetic semiconductor films grown on insulating glass substrates only show positive anomalous Hall effect. The enhanced negative anomalous Hall effect is attributed to the interfacial Rashba spin–orbit coupling in MnxSi1−x/SiO2/Si p–i–n junctions.
Fig. 2(a)–(d) show various Hall resistivity loops ρxy–H for Mn0.48Si0.52 films with different thicknesses, measured at different temperatures, and grown on different substrates. The common features can be seen from Fig. 2(a)–(d) that the positive Hall resistivity of all Mn0.48Si0.52 films are almost the same in low temperature range, which decreases gradually with increasing temperature from 5 K and almost disappears up to 150 K. It is clear that the positive Hall resistivity below 150 K almost does not depend on the thickness of the films (above 20 nm) and substrate (Si or glass). Our previous studies22 indicate that the observed positive Hall resistivity of Mn0.48Si0.52 films is mainly contributed by anomalous Hall resistivity and the ordinary Hall resistivity of the p-type charge carriers is negligible at low temperature below 150 K.
However, as compared with the reference Mn0.48Si0.52 films grown on glass substrates in Fig. 2(d), the Hall resistivity of the 20 nm Mn0.48Si0.52 films grown on near-intrinsic n-type Si substrates (i.e., Mn0.48Si0.52/SiO2/Si p–i–n junctions) in Fig. 2(a) shows quite different behavior. Fig. 2(a) indicates that the sign of the Mn0.48Si0.52/SiO2/Si p–i–n junctions is positive and the magnitude of the Hall resistivity gradually decreases as the temperature increases from 5 to 150 K, but above 170 K, the sign of the Hall resistivity becomes negative and the magnitude of the Hall resistivity increases rapidly to a maximum of 10 μΩ cm around 200 K, which is much stronger than the Hall resistivity at 5 K. Further increasing temperature from 200 to 300 K, the magnitude of the Hall resistivity gradually decreases again. Moreover, it is clear that the negative Hall resistivity around the temperature of 200 K is mainly due to the contribution of the anomalous Hall resistivity in the low field range below 30 kOe. And the positive slope of the Hall resistivity loops in the high field range above 30 kOe indicates that the ordinary Hall resistivity is significantly strong and the conducting charge carriers are p-type (holes) in the Mn0.48Si0.52 layer of the Mn0.48Si0.52/SiO2/Si p–i–n junctions. It is worthy to mention that the electrical shunt effect of the 0.5 mm thick near-intrinsic n-type Si substrate with 1 nm SiO2 native oxide layer is negligible as compared with the 20 nm Mn0.48Si0.52 film. Furthermore, Fig. 2(b) and (c) indicate that almost the same positive Hall resistivity was observed in the low temperature range for Mn0.48Si0.52 films of 100 nm and 300 nm in thickness, which means that the positive Hall resistivity is a bulk effect (independent on the thickness of Mn0.48Si0.52 films). But as the thickness of Mn0.48Si0.52 films increases, the magnitude of the negative Hall resistivity obviously decreases, which means that the negative Hall resistivity of the Mn0.48Si0.52 films is related to the interface of the MnxSi1−x/SiO2/Si p–i–n junctions.
In order to verify the interfacial effects of the Mn0.48Si0.52/SiO2/Si p–i–n junctions on the electrical transport, Fig. 3(a)–(c) show the temperature dependence of the longitudinal conductivity σxx for Mn0.48Si0.52 films on different substrates with various thicknesses. With increasing temperature, the longitudinal conductivity σxx for all the Mn0.48Si0.52 films increases very slowly. This is the typical electrical transport behavior on the metallic side of the metal-insulator transition,23 which can be described by the following equation
| σxx = σ0 + c1T1/2 + c2T. | (1) |
Here, the first term σ0 is the conductivity at T = 0 K, the second one c1T1/2 arises from the Coulomb interaction of carriers, and the third one c2T originates from the inelastic electron-phonon scattering of the weakly localized carriers.23–26 As illustrated in Fig. 3(a)–(c), the longitudinal conductivity σxx of the single Mn0.48Si0.52 films can be well fitted by eqn (1) in the whole experimental temperature range from 5 to 300 K except Fig. 3(a). It is clear in Fig. 3(a) that the experimental conductivity of 20 nm Mn0.48Si0.52 films grown on the near-intrinsic n-type Si substrate begins to deviate from the fitting line from 150 to 300 K and becomes 2.5% more than the fitting value at 200 K. On the other hand, as compared with the Mn0.48Si0.52 films in Fig. 3(b) and (c), we did not observe any difference in microstructure and magnetism for the Mn0.48Si0.52 films in Fig. 3(a). However, it is very important to notice that the enhanced conductivity in the temperature range from 150 to 300 K in Fig. 3(a) corresponds to the enhanced negative Hall resistivity in Fig. 2(a) in the same temperature range. Therefore, we conclude that the enhanced conductivity in Fig. 3(a) is due to the decrease of the depletion layer in the MnxSi1−x/SiO2/Si p–i–n junctions as the temperature increases from 150 to 300 K. Obviously, this interfacial effect becomes relatively weak as the Mn0.48Si0.52 films become thick, as shown in Fig. 2(a)–(c), 3(a) and (b).
To gain more insight into the enhanced negative AHE due to the interfacial effect for Mn0.48Si0.52/SiO2/Si p–i–n junctions, we seek to analyze the current–voltage I–V characteristics of the Mn0.48Si0.52/SiO2/Si p–i–n junction at various temperatures in the forward and reverse bias conditions as shown in Fig. 4. The I–V curves of the junction exhibit rectification characteristics. The junction is on turn-on state in the forward bias and is on turn-off state in the reverse bias below about 150 K. Comparing Fig. 4 with 3(a) and 2(a), we can derive that there exist no conducting carriers (electrons or holes) in the depletion layer of the MnxSi1−x/SiO2/Si p–i–n junction below 150 K without enough bias voltage. This means that when the longitudinal conductivity and the Hall resistivity were measured by applying an in-plane current in the Mn0.48Si0.52 layer, the Mn0.48Si0.52 layer just behaves like a single film grown on the insulating substrate due to the existence of the interfacial depletion layer at low temperature (see Fig. 2 and 3).
On the other hand, as the temperature increases, more carriers are excited to the conducting states and their kinetic energy becomes big. At the same time, both the barrier height and depletion layer thickness of Mn0.48Si0.52/SiO2/Si p–i–n junctions decrease with increasing temperature. In this case, the rectification effect gradually decays with increasing the temperature from 150 to 300 K as shown in Fig. 4, where significant current can be observed at the small forward and reverse bias voltage. This means that when the longitudinal conductivity and the Hall resistivity were measured by applying an in-plane current in the Mn0.48Si0.52 layer at high temperature, the conducting carriers can easily cross the thin and low barrier of the Mn0.48Si0.52/SiO2/Si p–i–n junctions. As a result, the interfacial Rashba spin–orbit coupling will act on the tunneling carriers across the barrier, which can be written as
, where p is the momentum of the conducting carrier with the effective mass m, σ is the vector of Pauli matrices, and ∇V is the potential gradient at the interface.27,28 As the first order approximation, the AHE is proportional to the spin–orbit coupling,17 and therefore the enhanced negative AHE of Mn0.48Si0.52/SiO2/Si p–i–n junctions in the high temperature range can be well explained by the Rashba spin–orbit coupling in the Mn0.48Si0.52/SiO2/Si p–i–n junction interface.
In order to further check the potential effects of the p–n junction, the SiO2 native oxide layer of the near-intrinsic n-type Si substrate was corroded, and the Mn0.48Si0.52/Si p–n junctions under the same sputtering conditions were prepared. Fig. 5(a) shows Hall resistivity loops ρxy–H of the 20 nm Mn0.48Si0.52 films grown on the near-intrinsic n-type Si substrates. As we mentioned before, the positive Hall resistivity of the Mn0.48Si0.52 films is almost the same below 150 K, which does not depend on the types of substrates. But the negative Hall resistivity gets to the maximum around 215 K, which is greatly enhanced as compared with that of Mn0.48Si0.52/SiO2/Si p–i–n junctions shown in Fig. 2(a). This means that the interfacial Rashba spin–orbit coupling can be further enhanced without the SiO2 native oxide interlayer, and therefore the negative Hall resistivity is greatly enhanced. Fig. 5(b) and (c) show the Hall resistivity loops ρxy–H of the same Mn0.48Si0.52 films of 20 nm but grown on n-type Si and p-type Si substrates, respectively. For the 20 nm Mn0.48Si0.52 films grown on n-type Si substrates in Fig. 5(b), the negative Hall resistivity at high temperature mainly comes from the ordinary Hall effect of the n-type substrate due to the strong shunting effect, and only very weak nonlinear component of the negative Hall resistivity originates from the anomalous Hall effect of the Mn0.48Si0.52 films due to the interfacial Rashba spin–orbit coupling. However, for the 20 nm Mn0.48Si0.52 films grown on p-type Si substrates in Fig. 5(c), we did not see any sign of the negative Hall resistivity, since both the Mn0.48Si0.52 films and the Si substrate are p-type. Therefore, Fig. 2 and 5 indicate that the enhanced negative anomalous Hall effect of the 20 nm Mn0.48Si0.52 films originates from the interfacial Rashba spin–orbit coupling.
It is also well known that the relationship Rs = aρxxp between anomalous Hall coefficient RS and the longitudinal resistivity ρxx is usually used to distinguish intrinsic, side-jump and skew scattering contributions.17 For the 20 nm Mn0.48Si0.52 films, the anomalous Hall resistivity originates from skew scattering mechanism, which is determined by the exponent p = 1 in the low temperature range. However, in the high temperature range above 150 K, the enhanced AHE itself does not saturate even up to the applied magnetic field of 60 kOe. Therefore, we could not well separate the ordinary Hall and anomalous Hall signals in the high temperature range. As a result, we could not give the relationship Rs = aρxxp above 150 K.
Finally we measured the magnetoresistance (MR) to check the possible effects of the Rashba spin–orbit coupling at the interface. Fig. 6 shows the magnetoresistance of the 20 nm Mn0.48Si0.52 films grown on the near-intrinsic n-type Si substrates. Both the electric current and magnetic field are applied in the film plane, and the magnetic field is perpendicular to (marked as ⊥) or parallel to (marked as ∥) the current. The MR is negative and does not saturate up to 60 kOe below 100 K. Moreover, the MR curves do not show any hysteresis and anisotropy for the magnetic field parallel to (perpendicular to) the current direction. The non-hysteresis negative magnetoresistance can be explained by the spin-dependent scattering between conducting carriers and local magnetic moments.
An obvious anisotropy of the magnetoresistance is observed around 200 K and the magnetoresistance becomes positive. This corresponds to the temperature range where the negative and enhanced AHE is observed. The anisotropy of the positive magnetoresistance can be explained by the Lorentz force which was felt by the conducting carriers in magnetic field. However, we could not observed the conventional anisotropic magnetoresistance of the ferromagnetic films from 5 to 300 K within the experimental errors, although there exist significant AHE and ferromagnetism in the low temperature range below 50 K.
| This journal is © The Royal Society of Chemistry 2016 |