Issue 40, 2016, Issue in Progress
From the journal:

RSC Advances

Aryne-induced dearomatized phosphonylation of electron-deficient azaarenes†

Kai Liu,a   Li-Li Liu,a   Cheng-Zhi Gu,a   Bin Dai*a  and  Lin He*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Autonomous Region, P. R. China
E-mail: db_tea@shzu.edu.cn, helin@shzu.edu.cn
Fax: +86-993-2057270

Abstract

An aryne-induced dearomatized phosphonylation reaction has been developed. Electron-deficient azaarenes such as quinolines, isoquinolines, phenanthroline and acridine undergo multicomponent reaction with arynes and dialkylphosphites to afford the corresponding dearomatized phosphonylated heterocycles in 50–90% yields.

Graphical abstract: Aryne-induced dearomatized phosphonylation of electron-deficient azaarenes

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Article information

DOI
https://doi.org/10.1039/C6RA02128J
Article type
Communication
Submitted
24 Jan 2016
Accepted
28 Mar 2016
First published
30 Mar 2016

RSC Adv., 2016,6, 33606-33610

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Aryne-induced dearomatized phosphonylation of electron-deficient azaarenes

K. Liu, L. Liu, C. Gu, B. Dai and L. He, RSC Adv., 2016, 6, 33606 DOI: 10.1039/C6RA02128J

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