Issue 43, 2016, Issue in Progress
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RSC Advances

Quantum chemical approach for highly durable anion exchange groups in solid-state alkaline fuel cells†

K. Matsuyama,a   H. Ohashi,a   S. Miyanishi,a   H. Ushiyamab  and  T. Yamaguchi*a  

* Corresponding authors

a Chemical Resources Laboratory, Tokyo Institute of Technology, R1-17 4259 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8503, Japan
E-mail: yamag@res.titech.ac.jp
Fax: +81-45-924-5253
Tel: +81-45-924-5254

b Department of Chemical System Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract

Durable anion exchange groups are required for solid-state alkaline fuel cells. In the present study, the lowest unoccupied molecular orbital (LUMO) was employed as a design guideline for durable anion exchange groups. The correlation between the LUMO and the durability of the anion exchange group was clarified.

Graphical abstract: Quantum chemical approach for highly durable anion exchange groups in solid-state alkaline fuel cells

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Article information

DOI
https://doi.org/10.1039/C5RA27939A
Article type
Communication
Submitted
29 Dec 2015
Accepted
06 Apr 2016
First published
07 Apr 2016

RSC Adv., 2016,6, 36269-36272

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Quantum chemical approach for highly durable anion exchange groups in solid-state alkaline fuel cells

K. Matsuyama, H. Ohashi, S. Miyanishi, H. Ushiyama and T. Yamaguchi, RSC Adv., 2016, 6, 36269 DOI: 10.1039/C5RA27939A

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