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Correction: Reaction mechanisms in ionic liquids: the kinetics and mechanism of the reaction of O,O-diethyl (2,4-dinitrophenyl) phosphate triester with secondary alicyclic amines

Paulina Pavez *, Daniela Millán , Javiera Morales , Mabel Rojas , Daniel Céspedes and José G. Santos
Facultad de Química. Pontificia Universidad Católica de Chile, Casilla 306, Santiago 6094411, Chile. E-mail: ppavezg@uc.cl; Fax: +56-02-26864744; Tel: +56-02-23541743

Received 22nd December 2015 , Accepted 22nd December 2015

First published on 12th January 2016


Abstract

Correction for ‘Reaction mechanisms in ionic liquids: the kinetics and mechanism of the reaction of O,O-diethyl (2,4-dinitrophenyl) phosphate triester with secondary alicyclic amines’ by Paulina Pavez et al., Org. Biomol. Chem., 2016, DOI: 10.1039/c5ob02128f.


The authors regret that there was an error in the formatting of Table 1. The correct table is shown below.
Table 1 Nucleophilic rate constants for the reaction of 1 with SA amines in [Bmim]BF4 and [Bmim]DCA at 25 °C ± 0.1
SA amines [Bmim]BF4 [Bmim]DCA
k PN/M−1 s−1 k ArN/M−1 s−1 k PN/M−1 s−1
Uncertainties quoted represent the standard deviation of at least three replicates.
Piperidine 0.89 ± 0.03 3.54 ± 0.13 7.60 ± 0.34
1-(2-Hydroxyethyl)piperazine 0.20 ± 0.01 0.65 ± 0.05 1.50 ± 0.05
Morpholine 0.068 ± 0.002 0.31 ± 0.01 0.55 ± 0.01


The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.


This journal is © The Royal Society of Chemistry 2016
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