Issue 17, 2016
From the journal:

Dalton Transactions

Addition of alkynes to digermynes: experimental insight into the reaction pathway†

Nada Y. Tashkandi,a   Laura C. Pavelka,a   Christine A. Caputo,b   Paul D. Boyle,a   Philip P. Powerb  and  Kim M. Baines*a  

* Corresponding authors

a Department of Chemistry, University of Western Ontario, London, Ontario, Canada
E-mail: kbaines2@uwo.ca

b Department of Chemistry, University of California at Davis, One Shields Avenue, Davis, California 95616, USA

Abstract

The addition of an alkynyl cyclopropyl mechanistic probe to a digermyne did not lead to any ring-opened rearrangement products indicating that the reaction pathway does not involve any vinylic radicals or cations and providing experimental insight into the addition of alkynes to digermynes.

Graphical abstract: Addition of alkynes to digermynes: experimental insight into the reaction pathway

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Article information

DOI
https://doi.org/10.1039/C6DT01015F
Article type
Communication
Submitted
15 Mar 2016
Accepted
01 Apr 2016
First published
11 Apr 2016

Dalton Trans., 2016,45, 7226-7230

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Addition of alkynes to digermynes: experimental insight into the reaction pathway

N. Y. Tashkandi, L. C. Pavelka, C. A. Caputo, P. D. Boyle, P. P. Power and K. M. Baines, Dalton Trans., 2016, 45, 7226 DOI: 10.1039/C6DT01015F

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