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DOI: 10.1039/C6CY90069K (Correction) Catal. Sci. Technol., 2016, 6, 5754-5755

Correction: A Pd–bisphosphine complex and organic functionalities immobilized on the same SiO2 surface: detailed characterization and its use as an efficient catalyst for allylation

Ken Motokura a, Koki Saitoh a, Hiroto Noda a, Wang-Jae Chun b, Akimitsu Miyaji a, Sho Yamaguchi a and Toshihide Baba *a
aDepartment of Chemical Science and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama, 226-8502, Japan. E-mail: tbaba@chemenv.titech.ac.jp
bGraduate School of Arts and Sciences, International Christian University, Mitaka, Tokyo, 181-8585, Japan

Received 24th June 2016 , Accepted 24th June 2016

First published on 29th June 2016

Abstract

Correction for ‘A Pd–bisphosphine complex and organic functionalities immobilized on the same SiO2 surface: detailed characterization and its use as an efficient catalyst for allylation’ by Ken Motokura et al., Catal. Sci. Technol., 2016, DOI: 10.1039/c6cy00593d.

In the above article, the chemical structure of the nucleophile displayed in entry 6 of Table 5 is incorrect. A corrected version of Table 5 is given below.
Table 5 The allylation catalyzed by SiO2/DABCO/PP-Pd under solvent-free conditionsa

image file: c6cy90069k-u1.tif
Entry Nucleophile (mmol) Pd (μmol) K2CO3 (mmol) Time (h) Yield (mono/di) (%) TONb
a Reaction conditions: nucleophile, allyl methyl carbonate (2.5 equiv.), K2CO3, SiO2/DABCO/PP-Pd, 70 °C, neat. Yield was determined by 1H NMR analysis using an internal standard. b TON was calculated as follows: TON = (moles of nucleophile) × [(yield of the mono-product) + 2 × (yield of the di-product)]/(moles of Pd). c 80 °C. d 100 °C.
1c image file: c6cy90069k-u2.tif 12.6 0.21 0.025 216 3/87 106[thin space (1/6-em)]000
2 image file: c6cy90069k-u3.tif 9.0 1.5 0.13 31 <1/>99 12[thin space (1/6-em)]000
3 image file: c6cy90069k-u4.tif 9.0 1.5 0.13 5 <1/93 11[thin space (1/6-em)]200
4 image file: c6cy90069k-u5.tif 9.0 1.5 0.13 48 <1/98 11[thin space (1/6-em)]800
5 image file: c6cy90069k-u6.tif 9.0 1.5 0.13 54 83/12 6400
6 image file: c6cy90069k-u7.tif 9.0 1.5 0.13 24 <1/98 11[thin space (1/6-em)]700
7d image file: c6cy90069k-u8.tif 9.0 1.5 0.13 31 <1/95 11[thin space (1/6-em)]400
8 image file: c6cy90069k-u9.tif 18.0 1.5 0.13 113 98/– 11[thin space (1/6-em)]700
9 image file: c6cy90069k-u10.tif 18.0 1.5 0.13 124 84/– 10[thin space (1/6-em)]100

The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.

This journal is © The Royal Society of Chemistry 2016
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